Uniform polyaniline nanofibers readily form using interfacial polymerization without the need for templates or functional dopants. The average diameter of the nanofibers can be tuned from 30 nm using hydrochloric acid to 120 nm using perchloric acid as observed via both scanning and transmission electron microscopy. When camphorsulfonic acid is employed, 50 nm average diameter fibers form. The measured Brunauer−Emmett−Teller surface area of the nanofibers increases as the average diameter decreases. Further characterization including molecular weight, optical spectroscopy, and electrical conductivity are presented. Interfacial polymerization is shown to be readily scalable to produce bulk quantities of nanofibers.The original research paper can be seen here.
A General Chemical Route to Polyaniline Nanofibers
sethfinley, , Electrospinning, Nanofibers, 0
Nanofibers of polymers were electrospun by creating an electrically charged jet of polymer solution at a pendent droplet. After...
sethfinley, , ceramic, Electrospinning, Nanofibers, Nanotubes, 0
Electrospinning is a remarkably simple method for generating nanofibers of polymers. When combined with conventional sol–gel processing, it provides...
sethfinley, , Ceramics, Nanofibers, 0
Hollow nanofibers with walls made of inorganic/polymer composites or ceramics have been prepared by electrospinning two immiscible liquids through...
sethfinley, , Electrospinning, Nanofibers, Polymers, 0
Uniform nanofibers composed of poly and its blends with poly(3-hexylthiophene) are formed by co-electrospinning their solutions with poly(vinyl pyrrolidone)...
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